Erbium-doped nanoparticles in silica-based optical fibres

Developing of new rare-earth (RE)-doped optical fibres for power amplifiers and lasers requires continuous improvements in the fibre spectroscopic properties (like shape and width of the gain curve, optical quantum efficiency, resistance to spectral hole burning and photodarkening,...). Silica glass as a host material for fibres has proved to be very attractive. However some potential applications of RE-doped fibres suffer from limitations in terms of spectroscopic properties resulting from clustering or inappropriate local environment when doped into silica. To this aim, we present a new route to modify some spectroscopic properties of rare-earth ions in silicabased fibers based on the incorporation of erbium ions in amorphous dielectric nanoparticles, grown in-situ in fiber preforms. By adding alkaline earth elements, in low concentration into silica, one can obtain a glass with an immiscibility gap. Then, phase separation occurs under an appropriate heat treatment. We investigated the role of three alkaline-earth elements: magnesium, calcium and strontium. We present the achieved stabilization of nanometric erbium-doped dielectric nanoparticles within the core of silica fibers. We present the nanoparticle dimensional characterization in fiber samples. We also show the spectroscopic characterisation of erbium in preform and fibre samples with different compositions. This new route could have important potentials in improving rare-earth doped fibre amplifiers and laser sources.